FISHER SCIENTIFIC -- BENZOIC ACID, A635000 -- -
===================== Product Identification ===================== Product ID:BENZOIC ACID, A635000 MSDS Date:12/12/1997 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:BENZOIC ACID CAS:65-85-0 RTECS #:DG0875000 = Wt:100. EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 1700 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES SEVERE EYE IRRITATION. MAY CAUSE EYE INJURY. SKIN: CAUSES SKIN IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA. MAY CAUSE DIGESTIVE T RACT DISTURBANCES. MAY CAUSE ALLERGIC REACTION. INHALATION: CAUSES RESPIRATORY TRACT IRRITATION. CHRONIC: NO INFORMATION FOUND. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCASNLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID IMMED. SKIN: GET MEDICAL AID. FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE REMOVI NG CONTAMD CLTHG & SHOES. INGEST: INDUCE VOMITING. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MEDICAL AID. INHAL: REMOVE FROM EXP OSURE TO FRESH AIR IMMED. GET MEDICAL AID IF COUGH OR OTHER SYMTPOMS APPEAR. NOTES TO PHYS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:=121.C, 249.8F Autoignition Temp:=574.C, 1065.2F Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL FOAM, OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPORS MAY FORM AN EXPLOSIVE MIXTURE WITH AIR. THIS MATERIAL IN SUFFICIENT QUANTITY AND REDUCED PARTICLE SIZE IS CAPABLE OF CREATING A DUST EXPLOSION. HEALTH: 2; FLAMMABILITY: 1; REACTIVITY: 0. ================== Accidental Release Measures ================== Spill Release Procedures:GEN INFO: USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENER ATING DUSTY CONDITIONS. ====================== Handling and Storage ====================== Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID INGESTION AND INHALATION. Other Precautions:KEEP AWAY FROM HEAT AND FLAME. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM STR ONG BASES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=249.C, 480.2F Melt/Freeze Pt:=122.C, 251.6F Vapor Pres:10 @ 96C Vapor Density:4.2(AIR=1) Spec Gravity:1.32 pH:2.8 @ STD SOLN Solubility in Water:2.9% @ 20C Appearance and Odor:WHITE SOLID, BENZENE-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS EXOTHERMICALLY WITH STRONG BASES, AND ITS WATER SOLUTION REACTS WITH METALS AND CAN GENERATE HYDROGEN GAS. INCOMPATIBLE WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:INCOMPATIBLE MATERIALS, STRONG OXIDANTS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, PHENOL, BENZENE. =================== Toxicological Information =================== Toxicological Information:CAS# 65-85-0: DG0875000. LD50/LC50: CAS# 65/85-0: ORAL,MOUSE: LD50 = 1940 MG/KG; ORAL,RAT: LD50 = 1700 MG/KG. EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROTOXICITY, MUTAGENICITY & OTHER ST UDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL, & OTHER: NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:SHIPPING NAME: BENZOIC ACID. HAZARD CLASS: 9.2. UN NUMBER: UN9094. PACKING GROUP: III. ADDITIONAL INFO: REGULATED LIMIT 230 KG. US DOT, IATA, RID/ADR, IMO: NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): FINAL RQ = 5000 POUNDS (2270 KG). SECTION 302 (TPQ): NONE OF CHEMS IN PROD HAVE A TPQ. SARA CODES: CAS # 65-85-0:ACUTE. SECTION 313: NO CHEMS ARE REPORTABLE UNDER SECTIONS 313. Federal Regulatory Information:TSCA: CAS# 65-85-0 IS LISTED ON TSCA INVENTORY. HLTH & SFTY RPTG LIST: NONE OF CHEMS ARE ON HLTH & SFTY RPTG LIST. CHEM TEST RULES: NONE OF CHEMS IN PROD ARE UNDER CHEM TEST RULE. SECTION 12B: NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN MATL HAVE SNUR UNDER TSCA. CLEAR AIR ACT: THIS MATL DOES NOT CNTN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT C NTN ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES NOT CNTN ANY CALSS 2 OZONE DEPLETORS. CLEAN WATER AC T: LISTED AS HAZ SUBSTANCE UNDER CWA. NONE OF CHEMS IN (OTHER INFO) State Regulatory Information:STATE: CAS# 65-85-0 CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NOEN OF CHEMICALS IN TH IS PRODUCT ARE LISTED. EUROPEAN/INTERNATIONAL REGS. EUROPEAN LABELING I/A/W EC DIRECTIVES. HAZARD SYMBOLS: NOT AVAILABLE. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.